Birefringence
Some materials are birefringent, it means that they have 2 refractive indexes. A light beam that enters such material is refracted at two different angles!
This characteristic is very useful in the characterisation of gemstones.
Calcite, shown below, is a birefringent crystal.Furthermore, if we look along the length of the crystal , the effect is stronger, because light travels a larger distance inside the crystal: